Asymmetric cross-coupling reaction of -alkyl grignard reagents with organic halides in the presence of a chiral phosphine-nickel complex as a catalyst

Selective carbon-carbon bond formation by cross-coupling of Grignard reagents with organic halides. Catalysis by nickel-phosphine complexes

Kohei Tamao, Koji Sumitani, Makoto Kumada · Journal of the American Chemical Society · 1972 · 1.3K citations

Natural Sciences, Chemistry, Catalysis +12

Asymmetric catalytic reduction with transition metal complexes. I. Catalytic system of rhodium(I) with (-)-2,3-0-isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)butane, a new chiral diphosphine

Henri B. Kagan, Tuan-Phat Dang · Journal of the American Chemical Society · 1972 · 1K citations

Natural Sciences, Chemistry, Catalysis +7

Activation of Grignard reagents by transition-metal complexes. A new and simple synthesis of trans-stilbenes and polyphenyls

Robert J. P. Corriu, J. MASSE · Journal of the Chemical Society Chemical Communications · 1972 · 642 citations

Natural Sciences, Chemistry, Organic Chemistry +4

Homogeneous catalysis in the decomposition of diazo compounds by copper chelates

H. NOZAKI, Hidemasa Takaya, S. Moriuti et al. · Tetrahedron · 1968 · 310 citations

Natural Sciences, Biochemistry, Chemistry +16

Alkyl group isomerization in the cross-coupling reaction of secondary alkyl Grignard reagents with organic halides in the presence of nickel-phosphine complexes as catalysts

Kohei Tamao, Yoshihisa Kiso, Koji Sumitani et al. · Journal of the American Chemical Society · 1972 · 203 citations

Natural Sciences, Chemistry, Catalysis +12