Publication | Open Access
Die Schwingungsspektren von MoO<sub>3</sub>.2 H<sub>2</sub>O und MoO<sub>2</sub>Cl<sub>2</sub> · H<sub>2</sub>O / Vibrational Spectra of MoO<sub>3</sub> · 2 H<sub>2</sub>O and MoO<sub>2</sub>Cl<sub>2</sub> · H<sub>2</sub>O
11
Citations
0
References
1972
Year
EngineeringMoo 2Moo 3ChemistryInorganic MaterialSpectroscopic PropertySpectra-structure CorrelationMolecular SpectroscopyOxide HeterostructuresMaterials ScienceInorganic ChemistryPhysicsPhysical ChemistryQuantum ChemistryHydrogenCrystallographyNatural SciencesSpectroscopyApplied PhysicsCl 2
The Raman and infrared spectra of MoO 3 ·2 H 2 O and MoO 2 Cl 2 · H 2 O have been assigned based on the known crystal structures of these compounds. In the region of the Mo-O-stretching frequencies the spectra of ΜοO 3 ·2Η 2 O and MoO 2 Cl 2 or WO 2 Cl 2 are very similar. The same is valid for MoO 2 Cl 2 H 2 O compared with MoO 3 . The frequency νas (Mo-O - Mo) depends highly on the ratio of the bond lengths of the two bridge bonds.