Biomass derived hard carbon used as a high performance anode material for sodium ion batteries

TLDR

A porous hard carbon was produced by pyrolyzing H3PO4‑treated pomelo peels at 700 °C in N₂, and sodium storage occurs via intercalation into disordered graphene layers, surface redox of O‑containing groups, and pore filling. The resulting hard carbon has a 3‑D porous network with 1272 m² g⁻¹ surface area, O/P functional groups, delivers 181 mAh g⁻¹ at 200 mA g⁻¹ after 220 cycles and 71 mAh g⁻¹ at 5 A g⁻¹, but shows only 27 % coulombic efficiency due to SEI formation and P‑group side reactions.

Abstract

A porous hard carbon material was synthesized by the simple pyrolysis of H3PO4-treated biomass, i.e., pomelo peels, at 700 °C in N2. The as-obtained hard carbon had a 3D connected porous structure and a large specific surface area of 1272 m2 g−1. XPS analysis showed that the carbon material was functionalized by O-containing and P-containing groups. The porous hard carbon was used as an anode for sodium ion batteries and exhibited good cycling stability and rate capability, delivering a capacity of 181 mA h g−1 at 200 mA g−1 after 220 cycles and retaining a capacity of 71 mA h g−1 at 5 A g−1. The sodium storage mechanisms of the porous hard carbon can be explained by Na+ intercalation into the disordered graphene layers, redox reaction of the surface O-containing functional groups and Na+ storage in the nanoscale pores. However, the porous hard carbon demonstrated a low coulombic efficiency of 27%, resulting from the formation of a solid electrolyte interphase film and the side reactions of surface phosphorus groups.