Enantioselective Palladium‐Catalyzed Decarboxylative Allylation of Carbazolones and Indolones: Formal Synthesis of (+)‐Kopsihainanine A

Abstract

Adding value: A four-step synthesis of enantioenriched carbazolone and indolone derivatives has been developed using an enantioselective Pd-catalyzed decarboxylative allylation. The scope of this reaction is broad, and the materials are suited for natural product synthesis, shown with the completion of a formal synthesis of (+)-kopsihainanine (see scheme). As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.