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Diastereoselective Palladium-Catalyzed α-Arylation of 4-Substituted Cyclohexyl Esters
36
Citations
36
References
2008
Year
Room TemperatureCross-coupling ReactionEngineering4-Substituted Cyclohexyl EstersOrganic ChemistryOrganometallic CatalysisCatalysisStereoselective SynthesisChemistryDiastereoselective Palladium-catalyzed ArylationAsymmetric CatalysisEnantioselective Synthesis
A diastereoselective palladium-catalyzed arylation of 4-substituted cyclohexyl esters has been developed. The reaction proceeds at room temperature in the presence of [(t-Bu3P)PdBr]2 providing products in up to 37:1 dr.
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