Concepedia

Ni(iii) vs. Ni(ii)-thiyl radical: charge-delocalisation in a binuclear Ni(iii)Ni(ii)-dithiolate complex

Neil D. J. Branscombe, Andrew Atkins, A. Marin-Becerra, Eric J. L. McInnes, Frank E. Mabbs, Jonathan McMaster, Martin Schröder

Chemical Communications · 2003 · 34 citations · 9 references

DOI

Concepts

Abstract

Multi-frequency EPR spectroscopy on 61Ni-labelled samples of [Ni2(L)]3+ confirms extensive charge-delocalisation between the Ni(III) centre and thiolate donors in the Ni(II)Ni(III) complex.

References

9

Crystal structure of the nickel–iron hydrogenase from Desulfovibrio gigas

Anne Volbeda, Marie‐Hélène Charon, C. Piras et al. · Nature · 1995 · 1.5K citations

, , +15

Structure of the [NiFe] Hydrogenase Active Site:  Evidence for Biologically Uncommon Fe Ligands

Anne Volbeda, Elsa D. Garcin, C. Piras et al. · Journal of the American Chemical Society · 1996 · 669 citations

, , +17

Electron Paramagnetic Resonance Studies of the Electronic Structures of Bis(maleonitriledithiolato)copper(II), -nickel(III), -cobalt(II), and -rhodium(II) Complexes

A. H. Maki, N. Edelstein, Alan Davison et al. · Journal of the American Chemical Society · 1964 · 301 citations

, , +15

Infrared-Spectroelectrochemical Characterization of the [NiFe] Hydrogenase of<i>Desulfovibrio gigas</i>

António L. De Lacey, E. Claude Hatchikian, Anne Volbeda et al. · Journal of the American Chemical Society · 1997 · 262 citations

, , +16

Nickel L-Edge Soft X-ray Spectroscopy of Nickel−Iron Hydrogenases and Model CompoundsEvidence for High-Spin Nickel(II) in the Active Enzyme

Hongxin Wang, Corie Y. Ralston, Daulat S. Patil et al. · Journal of the American Chemical Society · 2000 · 152 citations

, , +17