Publication | Closed Access
Spinodal decomposition in a binary fluid
30
Citations
15
References
1993
Year
Quantum LiquidBinary FluidEngineeringFluid MechanicsScattered IntensityMagnetic ResonanceChemistryLight Scattering SpectroscopyPhase SeparationMolecular KineticsOptical SpectroscopyPhotophysical PropertyBiophysicsPhysicsPhotochemistryPhysical ChemistryQuantum ChemistryMultiphase FlowNatural SciencesSpectroscopyLight ScatteringChemical KineticsSample Temperature
Light scattering has been used to study a mixture of 3-methylpentane and nitroethane undergoing spinodal decompositon. The scattered intensity has been measured in absolute units allowing the first test of theory with no adjustable parameters. The measured structure factor does not evolve according to theory even when the initial fluctuations are taken into account. We believe the reason is that the evolving concentration field causes the sample temperature to change continuously throughout the decomposition process.
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