Screen Printed Thin Film CdS/CdTe Solar Cell

Abstract

Thin film CdS/CdTe solar cells with an efficiency of 6.3 % have been prepared on a borosilicate glass substrate of 4s×4 cm2 by successively repeating screen printing and heating (sintering) of each paste of CdS, CdTe and C. The CdS paste consists of CdS, CdCl2, GaCl2 and propylene glycol (PG). The CdTe paste contains CdCl2 and PG, and the C paste contains PG and a small amount of acceptor impurity. During the heating of C paste, an n·CdS/p·CdTe heterojunction is formed. In the most efficient cell, the peak of electron voltaic effect exists within 1 µm of the CdTe side from the CdS/CdTe metallurgical boundary. The C electrode cell is more stable than the previous Cu2Te electrode cell for an accelerated life test. From 25 elemental cells with 4×4 cm2 substrate, a 1 watt module has tentatively been constructed with a module efficiency of 2.9 %.