Concepedia

Oxidation of Cyclopentene with Hydrogen Peroxide Catalyzed by 12-Heteropoly Acids

Hiroshi Furukawa, Teiji Nakamura, Hiroyuki Inagaki, Eiichiro Nishikawa, Chihiro Imai, Makoto Misono

Chemistry Letters · 1988 · 60 citations · 3 references

DOI

Concepts

Abstract

Abstract 12-Heteropoly acids exhibited high performance for selective oxidation of cyclopentene to glutaraldehyde with hydrogen peroxide. Especially, heteropoly acids with mixed addenda atoms of Mo and W, H3PMo12−xWxO40(x=1–9), showed excellent results.

References

3

Catalysis by Heteropoly Compounds. III. The Structure and Properties of 12-Heteropolyacids of Molybdenum and Tungsten (H3PMo12−<i>x</i>W<i>x</i>O40) and Their Salts Pertinent to Heterogeneous Catalysis

Makoto Misono, Noritaka Mizuno, Koichi Katamura et al. · Bulletin of the Chemical Society of Japan · 1982 · 242 citations · Full text

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The role of peroxymetallation in selective oxidative processes

Hubert Mimoun · Journal of Molecular Catalysis · 1980 · 182 citations

, , +11

Epoxidation of Allylic Alcohols with Hydrogen Peroxide Catalyzed by [PMO<sub>12</sub>O<sub>40</sub>]<sup>3-</sup>[C<sub>5</sub>H<sub>5</sub>N<sup>+</sup>(CH<sub>2</sub>)<sub>15</sub>CH<sub>3</sub>]<sub>3</sub>

Yasuhiro Matoba, Hiroshi Inoue, Jun-Ichi Akagi et al. · Synthetic Communications · 1984 · 113 citations

, , +7