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Epoxidation of Allylic Alcohols with Hydrogen Peroxide Catalyzed by [PMO<sub>12</sub>O<sub>40</sub>]<sup>3-</sup>[C<sub>5</sub>H<sub>5</sub>N<sup>+</sup>(CH<sub>2</sub>)<sub>15</sub>CH<sub>3</sub>]<sub>3</sub>
113
Citations
6
References
1984
Year
Chemical EngineeringOrganic SolventEngineeringIndustrial CatalysisCatalytic SynthesisAllylic AlcoholsOrganic ChemistryCatalysisHomogeneous CatalysisChemistryDeoxygenationW-based Heteropoly Acids
Abstract Applicatims a Mo- and W-based heteropoly acids (HPA) as a catalyst in the oxidation of olefins have extensively been investigated1. However, a patent work is only attempted concerning the evoxidatim of olefins with H202 by HPA2) since the oxirane ring is cleaved because of a strong acidity of HPA itself. Herein, an effective epoxidatim of some allylic alcohols with H202 by a new Mo-species (MPCP), which was prepared from 12-molybdatophosphoric acid (H3PMo12040) and cetylpyridinium chloride (C5H5N (CH2), 15CH3- C1-) under two-phase conditions using chloroform as an organic solvent, is described.
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