Studies of Organosulfur Compounds. IX. The Preparation of Organometal IVb Esters of Aromatic Thio Acid

Shinzi Kato, Wataru Akada, Masateru Mizuta, Yoshio Ishii

Bulletin of the Chemical Society of Japan · 1973 · 40 citations · 7 references

DOIFull text

Open access

Concepts

Abstract

Abstract It was found that the reactions of potassium salts of aromatic thio acid with chlorotrimethylsilane gave the corresponding thionoacyloxysilanes [ArC(S)OSi(CH3)3]. On the other hand, the reactions with chlorotrimethylgermanes or -stannane gave the corresponding thiol esters [ArC(O)SM(CH3)3, M: Ge, or Sn] containing the sulfur-metal (IVb) linkage in almost quantitative yields.

References

7