Preparation of MCM-41 type silica-bound manganese(III) Schiff-base complexes

Concepts

Natural SciencesChemistryMaterials ScienceInorganic ChemistrySurface ChemistrySurface ScienceCoordination ChemistryInorganic SynthesisLigand BindingMetal-ligand BondingMineral Surface ChemistryTransition Metal ComplexesLigand ExchangeLigand Exchange ReactionsManganese ChelationManganese ChemistryMetal Ligand CoordinationPorous Surface StructureSilica Surface Functionalization

Abstract

Pentadentate ligands (salpr) anchored to the surface of MCM-41 type silica through covalently linked organic moieties are further converted into MnIII(salpr) complexes by ligand exchange without loss of the regular porous structure of the support.

References

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