Journal of the American Chemical Society · 1980 · 119 citations · 0 references
Natural SciencesChemistryCatalysisOrganic ChemistryPolymer ChemistryCatalyst PreparationCatalytic MaterialsCoordination ChemistryCoordination PolymersPolymerization ChemistrySupported CatalystsCatalyst Structure - Activity RelationshipsCatalytic FunctionalizationResearch ArticlesSchiff Base Catalysis
Synthetic procedures for attaching multidentate amines to organic polymers are described. These materials form the basis for the preparation of a wide variety of macrocyclic and chelating ligands that can be covalently attached to polymers. The reaction to produce Schiff base chelates is described and a series of covalently attached metal complexes prepared and identified. These systems have potential as catalysts for organic oxidations. (Author)