Concepedia

Neocuproine–KOtBu promoted intramolecular cross coupling to approach fused rings

Chang‐Liang Sun, Yifan Gu, Wei‐Ping Huang, Zhang‐Jie Shi

Chemical Communications · 2011 · 154 citations · 24 references

DOI

Concepts

Abstract

Polycycles can be produced with different linkages (A, B = O, N, C, S) by constructing biaryl C-C bonds via neocuproine-KO(t)Bu promoted cross coupling between C-Xs and C-Hs.

References

24

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Organocatalysis in Cross-Coupling: DMEDA-Catalyzed Direct C−H Arylation of Unactivated Benzene

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<i>tert</i>-Butoxide-Mediated Arylation of Benzene with Aryl Halides in the Presence of a Catalytic 1,10-Phenanthroline Derivative

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