Well Treatment Fluids Prepared with Oilfield Produced Water

Abstract

Abstract Oilfield produced water usually comprises both the formation water and injected fluids from prior treatments. Produced water may be environmentally hazardous and usually contains bacteria, hydrocarbons, and high levels of dissolved salts. As such, the proper disposal of produced water is often expensive. Meanwhile, fresh water used to formulate oilfield treatment fluids is becoming more costly and more difficult to obtain. Operators, as well as service companies, have therefore shown a strong desire to use produced water in field operations to reduce costs. Consequently, a series of laboratory experiments have been performed to optimize the viscosity profile of fracturing fluids prepared with produced water. Preparation of polysaccharide-based fracturing fluids with produced water frequently resulted in fluids with poor viscosity profiles despite the fact that the produced water was pretreated with biocide. Furthermore, the problem could not be resolved by just adding more biocide. In a number of representative cases, the guar-based fracturing fluids, prepared with produced water and regular biocide, quickly lost their viscosity after hydration, possibly because of the degradation of the guar by the bacterial enzymes in the produced water. A new fluid stabilizer was recently invented to address the problem, and it was observed that the addition of the stabilizer dramatically extended the lifetime of the polysaccharide-based fracturing fluids prepared with produced water. The fluid stabilizer was simply added to produced water prior to mixing the polymer. The polysaccharide-based fluids prepared with the stabilizer-treated produced water showed stable viscosity profiles at both surface and bottomhole temperatures. The use of the fluid stabilizer has greatly enhanced the fluid performance and job efficiency since its initial introduction in the field in June 2008 and was implemented in about 80 successful fracturing and sand control jobs by the end of 2008. The invention and successful application of the fluid stabilizer have reduced the operating costs for the operators and service companies. At the same time, this new technology has also helped improve the environment by cutting the fresh water usage in the field. This paper will discuss the chemistry, experimental studies, and case histories.