Concepedia

Formation of a long-lived charge-separated state of a zinc phthalocyanine-perylenediimide dyad by complexation with magnesium ion

Shunichi Fukuzumi, Kei Ohkubo, Javier Ortíz, Ana M. Gutiérrez, Fernando Fernández‐Lázaro, Ángela Sastre‐Santos

Chemical Communications · 2005 · 97 citations · 21 references

DOI

Concepts

Abstract

Photoexcitation of a zinc phthalocyanine-perylenediimide (ZnPc-PDI) dyad affords the triplet excited state without the fluorescence emission, whereas addition of Mg2+ to the photoexcited ZnPc-PDI results in formation of a long-lived charge-separated state (ZnPc.+-PDI.-/Mg2+) in which PDI.- forms a complex with Mg2+.

References

21

Mimicking Photosynthetic Solar Energy Transduction

Devens Gust, Thomas A. Moore, Ana L. Moore · Accounts of Chemical Research · 2000 · 2.1K citations

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Charge Separation in a Novel Artificial Photosynthetic Reaction Center Lives 380 ms

Hiroshi Imahori, Dirk M. Guldi, Koichi Tamaki et al. · Journal of the American Chemical Society · 2001 · 515 citations

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Conducting Stacked Metallophthalocyanines and Related Compounds

Michael Hanack, Manuela Lang · Advanced Materials · 1994 · 448 citations

, , +12

Charge Transport in Photofunctional Nanoparticles Self-Assembled from Zinc 5,10,15,20-Tetrakis(perylenediimide)porphyrin Building Blocks

Tamar van der Boom, Ryan T. Hayes, Yongyu Zhao et al. · Journal of the American Chemical Society · 2002 · 391 citations

, , +17

Photochemistry of 3,4,9,10-perylenetetracarboxylic dianhydride dyes. 3. Singlet and triplet excited-state properties of the bis(2,5-di-tert-butylphenyl)imide derivative

William E. Ford, Prashant V. Kamat · The Journal of Physical Chemistry · 1987 · 361 citations

, , +14