Physical Review · 1938 · 173 citations · 3 references
Natural SciencesMaterials ScienceOpticsSpectroscopyThin FilmsAbsorption SpectroscopyOptical Thin FilmsThin Film Optical PropertiesAbsorption Line BroadeningAbsorption Spectrum CalculationDispersion CurvesDispersion EffectsOptical Absorption CoefficientSpectral Absorption CoefficientsSpectral Line IntensitiesSpectral Line Shapes
The study examines absorption in a spectral band where overlapping lines with a dispersion form influence the overall absorption. The authors solve analytically for a periodic line pattern of equal intensity S, width 2α, spacing d, deriving simple expressions for small and large α/d and showing that the resulting transmission formula can replace the mean absorption coefficient in radiative‑transfer equations. For large α/d, the transmission through a layer of thickness x follows I=I₀ exp[−(Sx/d) tanh(2π α/d)], which provides a good mean approximation even when α/d is small, whereas the true transmission deviates from an exponential form.
The note deals with the absorption of a band in which the lines have the dispersion form; the effect of the overlapping of neighboring lines upon the absorption is taken into account. The analytical problem can be solved for a periodic pattern of lines with equal intensity $S$, width $2\ensuremath{\alpha}$ and distance $d$ from each other. Simple expressions are derived for the limiting cases of small $\frac{\ensuremath{\alpha}}{d}$ (formula (8)) and large $\frac{\ensuremath{\alpha}}{d}$. In the latter case the transmission by a layer of thickness $x$ is given by $I={I}_{0}{e}^{\ensuremath{-}(\frac{\mathrm{Sx}}{d})tanh(\frac{2\ensuremath{\pi}\ensuremath{\alpha}}{d})}.$ It appears that this formula gives a fairly good mean approximation even for small values of $\frac{\ensuremath{\alpha}}{d}$, while the true transmission in this case is not exponential. It is shown that in problems of radiative transfer and radiative equilibria this approximate formula for the transmission can be used; i.e. the factor of $x$ in the above exponent may be substituted in the equations of transfer as equivalent of a mean absorption coefficient.
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The Shape and Intensities of Infra-Red Absorption Lines
David M. Dennison · Physical Review · 1928 · 88 citations
Natural Sciences, Chemistry, Physics +17
The Intensity of Infrared Absorption Bands
Lorne A. Matheson · Physical Review · 1932 · 37 citations