Concepedia

Direct Proof for OMn<sup>v</sup> (salen) Complexes

Derek Feichtinger, Dietmar A. Plattner

Angewandte Chemie International Edition in English · 1997 · 195 citations · 22 references

DOI

Concepts

Abstract

Electrospray mass spectroscopy has finally provided proof for the formation of oxomanganese(v) complexes such as 1 under the conditions of the Kochi-Jacobson-Katsuki epoxidation. Collision of 1 with olefins or sulfides in the gas phase regenerates the initial (salen)MNIII complexes by transfer of the oxygen atom.

References

22

Enantioselective epoxidation of unfunctionalized olefins catalyzed by salen manganese complexes

Wei Zhang, Jennifer L. Loebach, Scott R. Wilson et al. · Journal of the American Chemical Society · 1990 · 1.6K citations

, , +13

Highly enantioselective epoxidation catalysts derived from 1,2-diaminocyclohexane

Eric N. Jacobsen, Wei Zhang, Alexander R. Muci et al. · Journal of the American Chemical Society · 1991 · 1K citations

, , +14

Epoxidation of olefins with cationic (salen)manganese(III) complexes. The modulation of catalytic activity by substituents

K. S. V. Srinivasan, Pascal Michaud, Jay K. Kochi · Journal of the American Chemical Society · 1986 · 805 citations

, , +11

Metal-Ligand Multiple Bonds

Eric A. Maatta · Organometallics · 1989 · 670 citations

Asymmetric olefin epoxidation with sodium hypochlorite catalyzed by easily prepared chiral manganese(III) salen complexes

Wei Zhang, Eric N. Jacobsen · The Journal of Organic Chemistry · 1991 · 480 citations

, , +8