Concepedia

Hydrolysis of phosphotriesters promoted by a zinc(II) complex bearing an alcohol pendant

Ismail O. Kady, Biao Tan, Zhanying Ho, Todd Scarborough

Journal of the Chemical Society Chemical Communications · 1995 · 32 citations · 11 references

DOI

Concepts

Abstract

A polyamine-zinc(II) complex with an alcohol pendant promotes the hydrolysis of diethyl(4-nitrophenyl)phosphate via transfer of the diethylphosphate group to its alkoxy pendant.

References

11

Roles of zinc(II) ion in phosphatases. A model study with zinc(II)-macrocyclic polyamine complexes

Tohru Koike, Eiichi Kimura · Journal of the American Chemical Society · 1991 · 334 citations

, , +7

Tridentate Chelate Compounds. II<sup>1</sup>

Harold A. Goodwin, Francis Lions · Journal of the American Chemical Society · 1959 · 298 citations

, , +5

The catalytic carboxyester hydrolysis by a new zinc(II) complex with an alcohol-pendant cyclen (1-(2-hydroxyethyl)-1,4,7,10-tetraazacyclododecane): A novel model for indirect activation of the serine nucleophile by zinc(II) in zinc enzymes

Tohru Koike, Satoko Kajitani, Ikushi Nakamura et al. · Journal of the American Chemical Society · 1995 · 185 citations

, , +15

Carboxyester Hydrolysis Promoted by a New Zinc(II) Macrocyclic Triamine Complex with an Alkoxide Pendant: A Model Study for the Serine Alkoxide Nucleophile in Zinc Enzymes

Eiichi Kimura, Ikushi Nakamura, Tohru Koike et al. · Journal of the American Chemical Society · 1994 · 127 citations

, , +14

Metal ion promoted phosphate ester hydrolysis. Intramolecular attack of coordinated hydroxide ion

Philip Hendry, Alan M. Sargeson · Journal of the American Chemical Society · 1989 · 111 citations

, , +7