Publication | Closed Access
Infrared Spectra of the Group II Halides: Zinc Halides and the Ionic Model
45
Citations
14
References
1962
Year
Crystal StructureBending VibrationsEngineeringChemistrySpectroscopic PropertySpectra-structure CorrelationIonic ModelGaseous Zncl2Inorganic ChemistryGroup Ii HalidesPhysicsInfrared SpectroscopyAtomic PhysicsPhysical ChemistryQuantum ChemistryGroup IiZinc HalidesNatural SciencesSpectroscopyApplied PhysicsMain Group Chemistry
The bending vibrations of gaseous ZnCl2 and ZnBr2 have been observed in the cesium iodide region at 295 and 225 cm—1, respectively. It is shown that a molecular model based on polarizable ions cannot account for the observed bending frequencies of the Group II dihalides.
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