Science · 1977 · 311 citations · 4 references
EngineeringChemical EngineeringMaterials ScienceSeparation ProcessesSeparation ScienceThermodynamicsEnergy Storage MaterialsMembrane FabricationMembrane Module DesignMembrane ProcessingMembrane SeparationMembrane ThermodynamicsEntropy ProductionFabricationFabrication TechniquesHydrogen SeparationMembrane Fabrication TechniquesMembrane ProcessesThermochemical Energy StorageThermochemical Reactions
The limitations of thermochemical energy storage devices are the limitations of Carnot devices. Entropy production entailed in product separation further limits the efficiency of thermochemical processes. Thus, high upper temperatures and few reaction steps are desirable. In this article, the one-step effusional separation of water into hydrogen and oxygen is considered. Membrane materials, design, and fabrication techniques are suggested. A parametric analysis of the process suggests that the idea is a tantalizing possibility.
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Thermochemical Hydrogen Generation
R. H. Wentorf, R. E. Hanneman · Science · 1974 · 76 citations
Thermochemical Water Decomposition Processes
Raúl E. Chao · Product R&D · 1974 · 36 citations