Collection of Czechoslovak Chemical Communications · 1983 · 16 citations · 0 references
Natural SciencesChemistryAnalytical ChemistryElectrochemistryPhysical ChemistryElectrolyte SolutionsIon Transport In ElectrolytesAqueous Electrolyte SolutionsAqueous ElectrolytesConcentrationConcentration DependenceElectrolytesEquilibrium In Electrolyte SolutionsIonic StrengthThermodynamics Of Electrolyte Solutions
Based on a hypothesis verified earlier, according to which the concentration dependence of apparent molar volumes of ions in aqueous solutions is caused by their dehydration due to the decrease of the volume concentration of water, a method for the calculation of the density of concentrated aqueous electrolytes from individual ionic constants is proposed. The theory is verified by comparing with experimental data from the literature (420 solutions of 57 electrolytes).