Concepedia

Luminescence from Neptunyl(VI) Species in Solution

Catherine Talbot-Eeckelaers, Simon J. A. Pope, Amanda J. Hynes, Roy Copping, Chris Jones, Robin J. Taylor, Stephen Faulkner, Daniel Sykes, Francis R. Livens, Iain May

Journal of the American Chemical Society · 2007 · 40 citations · 11 references

DOI

Concepts

Abstract

The luminescence from the neptunyl(VI) ion and its polyoxometallate complexes has been investigated in solution for the first time. Emission occurs in the near-IR and is quenched effectively by O−H oscillators in the hydrated ion. The polyoxometallate complexes exclude solvent from the neptunyl coordination sphere and have much more intense and longer-lived emission spectra.

References

11

Lanthanide Complexes for Luminescence Imaging Applications

Stephen Faulkner, Simon J. A. Pope, Benjamin P. Burton‐Pye · Applied Spectroscopy Reviews · 2005 · 446 citations

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Photosensitized Near Infrared Luminescence of Ytterbium(III) in Proteins and Complexes Occurs via an Internal Redox Process

William DeW. Horrocks, James P. Bolender, Wendy D. Smith et al. · Journal of the American Chemical Society · 1997 · 304 citations

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Uranium complexes of multidentate N-donor ligands

Jonathan L. Sessler, Patricia J. Melfi, G. Dan Pantoş · Coordination Chemistry Reviews · 2005 · 276 citations

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Spectrophotometry of Neptunium in Perchloric Acid Solutions<sup>1</sup>

R. Sjoblom, J. C. Hindman · Journal of the American Chemical Society · 1951 · 123 citations

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On the performance of the intermediate Hamiltonian Fock-space coupled-cluster method on linear triatomic molecules: The electronic spectra of NpO2+, NpO22+, and PuO22+

Ivan Infante, André Severo Pereira Gomes, Lucas Visscher · The Journal of Chemical Physics · 2006 · 70 citations · Full text

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