Angewandte Chemie International Edition in English · 1993 · 150 citations · 11 references
Natural SciencesChemistryMedicinal ChemistryCrystal StructureOrganic ChemistrySolid-state ChemistryCluster ChemistryCoordination ChemistryCoordination PolymersPolymer StructureSupramolecular PolymersTransition Metal ComplexesMetal-ligand Coordination PolymersSupramolecular Coordination ChemistrySupramolecular Coordination ComplexesThree-dimensional Coordination PolymersTwo-dimensional Coordination Polymers
An unusual two-dimensional mesh of CuII ions is found in complex 1(see picture); the metal atoms are bridged by oxalato (ox) and bipyrimidine (bpym) ligands to form ringshaped hexamers. Variable-temperature magnetic susceptibility measurements indicate that antiferromagnetic coupling between the Cu atoms occurs.
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