Publication | Closed Access
Valence Tautomeric Transitions with Thermal Hysteresis around Room Temperature and Photoinduced Effects Observed in a Cobalt−Tetraoxolene Complex
206
Citations
26
References
2006
Year
EngineeringValence Tautomeric TransitionChemistryElectronic Excited StateInorganic CompoundThermal HysteresisQuantum MaterialsValence TautomerismCobalt−tetraoxolene ComplexValence Tautomeric TransitionsMaterials ScienceInorganic ChemistryPhysical ChemistryQuantum ChemistryCrystallographyInorganic SynthesisNatural SciencesCoordination ComplexCondensed Matter PhysicsApplied PhysicsMolecular ComplexDinuclear Complex
A dinuclear complex, [(CoTPA)2(DHBQ)](PF6)3, has been successfully synthesized that exhibits a valence tautomeric transition with a distinct hysteresis effect (13 K) around room temperature and photoinduced valence tautomerism under low temperature.
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