Synthesis of (±)-hirsutene by a catalytic allylpalladium-alkyne cyclization/carbonylation cascade

A synthetic method for formyl→ethynyl conversion (RCHO→RCCH or RCCR′)

E. J. Corey, P.L. Fuchs · Tetrahedron Letters · 1972 · 1.6K citations

Natural Sciences, Chemical Engineering, Chemistry +7

Organoselenium chemistry. A facile one-step synthesis of alkyl aryl selenides from alcohols

Paul A. Grieco, S. GILMAN, Mugio Nishizawa · The Journal of Organic Chemistry · 1976 · 649 citations

Natural Sciences, Chemistry, Analytical Chemistry +4

Vicinal diol cyclic sulfates. Like epoxides only more reactive

Yun Gao, K. Barry Sharpless · Journal of the American Chemical Society · 1988 · 542 citations

Natural Sciences, Chemistry, Analytical Toxicology +5

The olefin insertion reaction

David L. Thorn, Roald Hoffmann · Journal of the American Chemical Society · 1978 · 302 citations

Social Sciences, Communication, Mass Communication +5

Olefin synthesis. Rate enhancement of the elimination of alkyl aryl selenoxides by electron-withdrawing substituents

K. Barry Sharpless, Michael W. Young · The Journal of Organic Chemistry · 1975 · 292 citations

Natural Sciences, Chemistry, Analytical Chemistry +9