Electronic and infrared absorption spectra of linear and cyclic C6+ in a neon matrix

Abstract

Electronic and infrared absorption spectra of mass-selected C6+, generated by dissociative electron impact ionization of C6Cl6 and C6Br6, have been recorded in 6 K neon matrices. Linear and cyclic forms of C6+ have been observed. The 2Pig<--Chi2Piu electronic transition of linear C6+ has its origin band at 646 nm whereas for the (2) 2B2<--Chi2A1 system of the cyclic isomer it lies at 570 nm. An infrared active fundamental mode in the ground electronic state of C6+ is observed at 2092 and 1972 cm(-1) for the linear and cyclic isomer, respectively.