Concepedia

The dinitrosyliron complex [Fe<sub>4</sub>(μ<sub>3</sub>-S)<sub>2</sub>(μ<sub>2</sub>-NO)<sub>2</sub>(NO)<sub>6</sub>]<sup>2−</sup> containing bridging nitroxyls: <sup>15</sup>N (NO) NMR analysis of the bridging and terminal NO-coordinate ligands

Shih‐Wey Yeh, Chih‐Chin Tsou, Wen‐Feng Liaw

Dalton Transactions · 2014 · 15 citations · 22 references

DOI

Concepts

Abstract

The fluxional terminal and semibridging NO-coordinate ligands of DNIC [Fe4(μ3-S)2(μ2-NO)2(NO)6](2-), a precursor of Roussin's black salt (RBS), are characterized by IR ν(NO), (15)N (NO) NMR and single-crystal X-ray diffraction.

References

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