Optics Express · 2010 · 38 citations · 20 references
EngineeringOrganic ElectronicsOrganic Solar CellInverted GeometryPhoto-electrochemical CellOptoelectronic DevicesPhotovoltaic DevicesChemistryPhotovoltaicsPhotodetectorsSolar Cell StructuresMetallic Top ElectrodesTunable Absorption AsymmetryElectrical EngineeringSolar PowerOptoelectronic MaterialsOrganic SemiconductorAbsorption AsymmetryElectrochemistryOrganic Charge-transfer CompoundSemiconducting PolymerTop AnodeSolar CellsOptoelectronicsSolar Cell Materials
Efficient semitransparent organic photovoltaic (OPV) cells are presented in an inverted geometry employing ZnS/ Ag/ WO₃ (ZAW) as a top anode and ITO/ Cs₂CO₃ as a bottom cathode. Upon identification of the light absorption that differs depending on the illumination direction, the degree of the absorption asymmetry is tuned by varying the ZAW structure to maximize the efficiency for one direction or to balance it for both directions. Power conversion efficiency close to that of conventional opaque OPV cells is demonstrated in semitransparent cells for the ITO side illumination by taking advantage of the internal reflection occurring at the organic/ZAW interface. Cells with efficiencies that are reduced but balanced for both illumination directions are also demonstrated.
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Polymer solar cells with enhanced open-circuit voltage and efficiency
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2.5% efficient organic plastic solar cells
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