Publication | Closed Access
Reversible Thermally and Photoinduced Electron Transfer in a Cyano‐Bridged {Fe<sub>2</sub>Co<sub>2</sub>} Square Complex
230
Citations
28
References
2010
Year
Magnetic PropertiesEngineeringMagnetic ResonanceExcitation Energy TransferChemistryCharge TransportReversible ThermallyElectron PhysicMagnetismPhotoinduced Electron TransferInorganic CompoundQuantum MaterialsSquare ComplexInorganic ChemistryPhotochemistryPhysicsTetranuclear CyanometalatePhysical ChemistryQuantum ChemistryPhotochromismTransition Metal ChalcogenidesPhotomagnetic StudiesMolecule-based MagnetNatural SciencesCoordination ComplexCondensed Matter PhysicsApplied PhysicsLight-induced ChangesFunctional Materials
Flip to be square: Structural, spectroscopic, magnetic, and photomagnetic studies conclusively demonstrate that a tetranuclear cyanometalate {Fe2Co2} complex undergoes reversible thermally and light-induced changes in its optical and magnetic properties. This bistability is induced by an intramolecular electron transfer, as observed in three-dimensional Co/Fe Prussian blue compounds (see picture).
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