Differential optical absorption spectroscopy system used for atmospheric mercury monitoring

Abstract

A high-resolution differential optical absorption spectroscopy (DOAS) system for long-path atmospheric pollution monitoring is described. The system, consisting of a broadband lamp and a dispersive, fast-scanning optical receiver, separated by a few kilometers, was used in measurements of different pollutants, highlighted by the monitoring of the local concentration of atomic mercury. Mercury levels in the ppt (1:10(12)) range were assessed by comparisons with laboratory measurements.