Concepedia

Tetrakis(dimethylamino)ethylene (TDAE) mediated addition of difluoromethyl anions to heteroaryl thiocyanates. A new simple access to heteroaryl–SCF2R derivatives

Thierry Billard, Bernard R. Langlois, Maurice Médebielle

Tetrahedron Letters · 2001 · 60 citations · 20 references

DOI

Concepts

References

20

Methods for the synthesis of gem-difluoromethylene compounds

Matthew J. Tozer, Timothée F. Herpin · Tetrahedron · 1996 · 398 citations

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Nucleophilic Trifluoromethylation of Carbonyl Compounds and Disulfides with Trifluoromethane and Silicon-Containing Bases

Sylvie Large, Nicolas Roques, Bernard R. Langlois · The Journal of Organic Chemistry · 2000 · 236 citations

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Preparation of trifluoromethyl sulfides or selenides from trifluoromethyl trimethylsilane and thiocyanates or selenocyanates

Thierry Billard, Sylvie Large, Bernard R. Langlois · Tetrahedron Letters · 1997 · 190 citations

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A direct synthesis of aryl thiocyanates using cerium(IV) ammonium nitrate

Vijay Nair, Tesmol G. George, Latha G. Nair et al. · Tetrahedron Letters · 1999 · 130 citations

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New Stable Reagents for the Nucleophilic Trifluoromethylation. 1. Trifluoromethylation of Carbonyl Compounds with <i>N</i>-Formylmorpholine Derivatives

Thierry Billard, Stefan Bruns, Bernard R. Langlois · Organic Letters · 2000 · 113 citations

, , +4