Koilands from thiophiles: mercury(ii) clusters from thiacalixarenes

Huriey Akdas, Ernest Graf, Mir Wais Hosseini, André De Cian, Alex Bilyk, Brian W. Skelton, George A. Koutsantonis, Ian Murray, Jack M. Harrowfield, Allan H. White

Chemical Communications · 2002 · 67 citations · 8 references

Concepts

Abstract

Tetra- and hexa-nuclear mercury(II) complexes have been obtained from tetrathiacalix[4]arene and tetramercaptotetrathiacalix[4]arene, respectively, and structurally characterised in the solid state; the complexes provide new digonal and trigonal receptors of the koiland type.

References

8