Journal of The Electrochemical Society · 1972 · 152 citations · 0 references
Natural SciencesMaterials EngineeringMaterials ScienceSurface ChemistrySurface EngineeringSurface ScienceCorrosion MechanismsCorrosion Of SteelsCorrosion TestingStainless SteelsSurface PhysicsChemical PropertiesPit Growth KineticsPit InitiationPit PropagationReference Electrode DesignReference Electrode MaterialsStainless Steel PittingThin Oxide Films
A scanning reference electrode has been used to measure the number of active pits on 304 stainless steels in ferric chloride solution with time. The probability of a pit deactivating has been discussed in terms of the physical and chemical properties of solid oxide films over the pit which were originally on the steel and undermined by the dissolution process. The properties of these films were varied by different surface preparations.