Radical-induced fragmentations of ketoepoxides

Radical-induced ring opening of epoxides. A convenient alternative to the wharton rearrangement

Derek H. R. Barton, Robyn S. Hay Motherwell, William B. Motherwell · Journal of the Chemical Society Perkin Transactions 1 · 1981 · 99 citations

Natural Sciences, Chemistry, Organic Chemistry +6

Synthesis of carbocyclic systems via radical-induced epoxide fragmentation

Viresh H. Rawal, Randall C. Newton, V. Krishnamurthy · The Journal of Organic Chemistry · 1990 · 74 citations

Natural Sciences, Chemistry, Analytical Chemistry +6

3-Amino-5-hydroxybenzoic acid as a key intermediate in ansamycin and maytansinoid biosynthesis

Jeffrey J. Kibby, Ian A. McDonald, Rodney W. Rickards · Journal of the Chemical Society Chemical Communications · 1980 · 62 citations

Life Sciences, Biochemistry, Microbiology +9

Radical reactions of vinyl epoxides via radical translocations by a novel 1,5-n-Bu3Sn group or a 1,5-hydrogen atom transfer

Sunggak Kim, Sangphil Lee, Jae Suk Koh · Journal of the American Chemical Society · 1991 · 60 citations

Natural Sciences, Chemistry, Catalysis +14

Ansamycin Biogenesis: Studies on a Novel Rifamycin Isolated from a Mutant Strain of <i>Nocardia mediterranei</i>

Richard White, E. Martinelli, Giancarlo Lancini · Proceedings of the National Academy of Sciences · 1974 · 54 citations · Full text

Life Sciences, Biochemistry, Microbiology +9