¹³C NMR spectra of adamantane derivatives

Abstract

Abstract The carbon‐13 chemical shifts of mono‐ and 1,3‐disubstituted adamantanes are reported. The effects caused by the substituents are compared with those met in aliphatic and alicyclic compounds. It is shown that the 1,4‐interactions have only minor importance in l‐substituted adamantanes. The influence of polar groups on the chemical shifts of γ‐ and δ‐carbon atoms is a typical ‘through‐the‐bonds’ interaction and correlates with inductive parameters of the substituents.