Characterization by infrared and Raman spectroscopy of matrix-isolated M(CO)5N2 (M = chromium, molybdenum, or tungsten) produced by photolysis of M(CO)6

Jeremy K. Burdett, Anthony J. Downs, Geoffrey P. Gaskill, Michael Graham, James J. Turner, Robert F. Turner

Inorganic Chemistry · 1978 · 49 citations · 25 references

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Abstract

46) Manganese salicylate complexes require higher ligand concentrations for stability than do the other aromatic polyhydroxy ligands.(47) Increasing the hydroxide concentration in glycerate solutions also favors the formation of the Mn(IIIB) complex.This may be explained by the fact that glycerate anions are better stabilized by increasing basicity.(48) C. G.

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