Publication | Closed Access
Efficient Tuning of LUMO Levels of 2,5,8,11-Substituted Perylenediimides via Copper Catalyzed Reactions
81
Citations
22
References
2011
Year
Combinatorial ChemistryEngineeringElectron Affinity2,5,8,11-Substituted PerylenediimidesOrganometallic ElectrochemistrySynthetic PhotochemistryOrganic ChemistryChemistryEfficient TuningChemical EngineeringNovel OrganocatalystsOrganic ElectrochemistryLumo LevelsOrganometallic CatalysisMaterials ScienceCatalysisTetracyano DerivativesSynthesis MethodInorganic SynthesisTetracyano PerylenediimideSynthetic Chemistry
Via one-step copper catalyzed procedures it was possible to synthesize 2,5,8,11-tetrabromo, tetrachloro, and tetracyano derivatives of perylenediimides. Characterization of optical and electrochemical properties of these materials proves substantial enhancement of the electron affinity, with a LUMO level as low as -4.4 eV in the case of the tetracyano perylenediimide.
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