Formal syntheses of (±)-Asterisca-3(15),6-diene and (±)-Pentalenene using Rh(I)-catalyzed [(5+2)+1] cycloaddition

The synthesis of carbocyclic eight-membered rings

Nicos A. Petasis, Michael A. Patane · Tetrahedron · 1992 · 325 citations

Natural Sciences, Chemistry, Medicinal Chemistry +11

A Computationally Designed Rh(I)-Catalyzed Two-Component [5+2+1] Cycloaddition of Ene-vinylcyclopropanes and CO for the Synthesis of Cyclooctenones

Yuanyuan Wang, Jingxin Wang, Jiachun Su et al. · Journal of the American Chemical Society · 2007 · 214 citations

Natural Sciences, Chemistry, Computational Design +16

Selective Construction of Carbocyclic Eight‐Membered Rings by Ring‐Closing Metathesis of Acyclic Precursors

Antoine Michaut, Jean Rodriguez · Angewandte Chemie International Edition · 2006 · 200 citations

Natural Sciences, Chemistry, Green Chemistry +10

Highly Efficient Chemoselective Deprotection of <i>O,O</i>-Acetals and <i>O,O</i>-Ketals Catalyzed by Molecular Iodine in Acetone

Jianwei Sun, Yanmei Dong, Liya Cao et al. · The Journal of Organic Chemistry · 2004 · 180 citations

Natural Sciences, Chemistry, Catalysis +10

Tandem Rh(I)-Catalyzed [(5+2)+1] Cycloaddition/Aldol Reaction for the Construction of Linear Triquinane Skeleton:  Total Syntheses of (±)-Hirsutene and (±)-1-Desoxyhypnophilin

Lei Jiao, Changxia Yuan, Zhi‐Xiang Yu · Journal of the American Chemical Society · 2008 · 160 citations

Natural Sciences, Chemistry, Medicinal Chemistry +14