NEW SYNTHETIC REACTIONS BASED ON 1-METHYL-2-FLUOROPYRIDINIUM SALTS. STEREOSPECIFIC PREPARATION OF THIOALCOHOLS FROM ALCOHOLS

Ko Hojo, Hiroshi Yoshino, Teruaki Mukaiyama

Chemistry Letters · 1977 · 35 citations · 9 references

Concepts

Abstract

Abstract Treatment of various alcohols with 1-methyl-2-fluoropyridinium salt and sodium N,N-dimethyldithiocarbamate afforded alkykl N,N-dimethyldithiocarbamates of inverted configuration. The latter compounds were converted to thioalcohols with retention.

References

9