Applied Optics · 1971 · 48 citations · 7 references
Natural SciencesChemistryAtmospheric ChemistryAtmospheric ScienceSpectroscopyAtmospheric Oxidation ProcessesAtmospheric Radical ChemistryEmission SpectroscopyOptical SpectroscopyOzone ChemistryPhotochemical KineticsOzoneOzone PhotochemistryOzone Reaction KineticsRate ConstantsReaction Rate CoefficientsReaction Rate EquationsVibrational BandsVibrational Energy Levels
The reaction of vibrationally excited hydroxyl with ozone was studied in a fast-flow system by observing the effect of ozone concentration on the intensity of hydroxyl emission bands in the 1.4-micro to 2.2-micro wavelength region. Fourier transform spectroscopy was used to obtain spectra of the faint emissions from the excited hydroxyl. Rate constants for the ozone-hydroxyl reaction were calculated for vibrational levels nu = 2 to nu = 9. The rate constants increased with vibrational level in a regular manner up to nu = 5. An abrupt increase occurred for nu = 6 relative to nu = 5, which may suggest a change in mechanism beginning at nu = 6.
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Atlas of the airglow spectrum 3000–12400 Å
V. I. Krassovsky, N. N. Shefov, V.I. Yarin · Planetary and Space Science · 1962 · 194 citations
Formation of Vibrationally Excited OH by the Reaction H + O_3
P. E. Charters, R. Glen Macdonald, J. C. Polanyi · Applied Optics · 1971 · 137 citations
Natural Sciences, Chemistry, Physics +13