Concepedia

Expedient Deuterolabeling of Polyphenols in Ionic LiquidsDCl/D<sub>2</sub>O under Microwave Irradiation

Ullastiina Hakala, Kristiina Wähälä

The Journal of Organic Chemistry · 2007 · 19 citations · 14 references

DOI

Concepts

Abstract

Postsynthetic regioselective aromatic ring H/D exchanges in polyphenolic compounds are rapidly performed in high yields and isotopic purities in ionic liquid-DCl/D2O under microwave irradiation. Other C-H bonds, including benzylic and lactone alpha-carbonyl sites, are not affected.

References

14

Ionic liquids and their heating behaviour during microwave irradiation – a state of the art report and challenge to assessment

Jens Hoffmann, Matthias Nüchter, Bernd Ondruschka et al. · Green Chemistry · 2003 · 211 citations

, , +12

The 2-Position of Imidazolium Ionic Liquids:  Substitution and Exchange

Scott T. Handy, Maurice Okello · The Journal of Organic Chemistry · 2005 · 203 citations

, , +8

Isotope dilution gas chromatographic-mass spectrometric method for the determination of lignans and isoflavonoids in human urine, including identification of genistein

Herman Adlercreutz, Theodore Fotsis, C. Bannwart et al. · Clinica Chimica Acta · 1991 · 197 citations

, , +10

Metabolism of the soy isoflavones daidzein, genistein and glycitein in human subjects.

Satu‐Maarit Heinonen, Antti Hoikkala, Kristiina Wähälä et al. · The Journal of Steroid Biochemistry and Molecular Biology · 2003 · 157 citations

, , +9

Microwave-assisted organic synthesis: one hundred reaction procedures

Choice Reviews Online · 2006 · 99 citations

, , +17