Raman and infrared spectra of carbonates of calcite structure

TLDR

Carbonate minerals exhibit distinct Raman and infrared absorption bands that serve as diagnostic signatures of their mineralogy. The study measured Raman and mid‑range infrared spectra of natural limestone and dolomite and calculated their lattice parameters (a, c, V) to characterize their crystal structures. Spectral analysis and X‑ray diffraction confirmed that limestone samples contain calcite structure and dolomite samples contain dolomite structure. © 2006 John Wiley & Sons, Ltd.

Abstract

Abstract The Raman and mid‐range infrared spectra have been measured on natural limestone and dolomite minerals. The carbonate minerals show four prominent absorption bands in the regions 1450–1420, 890–870, 720–700 and 1000–1100 cm −1 . The positions of the wavenumbers are unique for each carbonate mineral and are thus diagnostic of their mineralogy. Calcite and dolomite groups are characterized by the Raman wavenumbers at 288 and 309 cm −1 and the infrared absorption bands at 712 and 728 cm −1 , respectively. The principal wavenumber at 1092 cm −1 in the limestone spectra is accompanied by two satellites with values of 1062 and 1075 cm −1 . The observed non‐split peaks ν 2 and ν 4 in the infrared spectra of limestone indicate the presence of calcite structure in all these samples. The principal reflections occurring at the d ‐spacings, 3.03482, 1.91658 and 1.87962 Å, confirm the presence of calcite structure in limestone minerals. The principal reflections occurring at the d ‐spacings, 3.037, 1.79179 and 2.19750 Å, confirm the existence of dolomite structure in the dolomite minerals. The calculated lattice parameters for the limestone minerals are: a = 4.9781 Å, c = 17.1188 Å and V = 367.392(Å) 3 and the corresponding values for the dolomite minerals are: a = 4.8247 Å, c = 15.9868 Å and V = 322.28 (Å) 3 . Copyright © 2006 John Wiley & Sons, Ltd.