Transport of Chloride Through an Unsaturated Field Soil

Abstract

A chloride tracer was applied to the surface of a vegetable field and then leached downward by rainfall and irrigation. Tracer concentrations in a vertical two‐dimensional region down to a depth of 2.4 m were monitored with suction cups that, were installed horizontally from a tunnel. The uniformly applied tracer pulse split into a slowly moving main pulse and a series of fast pulses. The first of the fast pulses reached a depth of 2.2 m after an infiltration of just 31 mm of natural rainfall, whereas the peak of the main pulse was still at a depth of 0.84 m by the end of the experiment after an infiltration of 0.853 m. The movement of the main pulse can be described by a convection‐dispersion process in a homogeneous medium, provided that time is replaced by cumulative infiltration. However, the values of the parameters that produce a maximum agreement between the model and the observed main pulse have no physical basis, and consequently prediction of solute movement, based on measurements of soil properties, is not possible.