Concepedia

Metal-free amidation of ether sp<sup>3</sup> C–H bonds with sulfonamides using PhI(OAc)<sub>2</sub>

Jesús Campos, S. K. Goforth, Robert H. Crabtree, T. Brent Gunnoe

RSC Advances · 2014 · 27 citations · 59 references

DOIFull text

Open access

Concepts

Abstract

Ether C–H bonds can be selectively amidated using simple sulfonamides and iodine oxidants in the absence of a metal catalyst.

References

59

Metal-Catalyzed Nitrogen-Atom Transfer Methods for the Oxidation of Aliphatic C–H Bonds

Jennifer L. Roizen, Mark Edwin Harvey, J. Du Bois · Accounts of Chemical Research · 2012 · 888 citations · Full text

Microwave Effects in Organic Synthesis: Myth or Reality?

C. Oliver Kappe, Bartholomäus Pieber, Doris Dallinger · Angewandte Chemie International Edition · 2012 · 528 citations

Intermolecular Oxidative C–N Bond Formation under Metal-Free Conditions: Control of Chemoselectivity between Aryl sp<sup>2</sup> and Benzylic sp<sup>3</sup> C–H Bond Imidation

Hyun Jin Kim, Jiyu Kim, Seung Hwan Cho et al. · Journal of the American Chemical Society · 2011 · 386 citations

, , +11

Organocatalytic, Oxidative, Intramolecular CH Bond Amination and Metal‐free Cross‐Amination of Unactivated Arenes at Ambient Temperature

Andrey P. Antonchick, Rajarshi Samanta, Katharina Kulikov et al. · Angewandte Chemie International Edition · 2011 · 380 citations

Copper-Catalyzed sp<sup>3</sup> C–H Amination

R.T. Gephart, Timothy H. Warren · Organometallics · 2012 · 321 citations

, , +9