Publication | Closed Access
Rh-Catalyzed Intermolecular Reactions of Alkynes with α-Diazoesters That Possess β-Hydrogens: Ligand-Based Control over Divergent Pathways
173
Citations
17
References
2006
Year
EngineeringDivergent PathwaysOrganic ChemistryChemistryGeneral MethodRh-catalyzed Intermolecular ReactionsNovel OrganocatalystsLigand-based ControlOrganometallic CatalysisCross-coupling ReactionBiochemistryRh-catalyzed CyclopropenationCatalysisAsymmetric CatalysisEnantioselective SynthesisBiomolecular EngineeringExpansion CascadeAlkene MetathesisNatural Sciences
A general method for Rh-catalyzed cyclopropenation is described, as is a Rh-catalyzed intermolecular alkyne insertion/Büchner ring expansion cascade. Ligand choice governs control over these divergent reaction pathways.
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