Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases · 1977 · 55 citations · 0 references
Natural SciencesChemistryPhysicsCondensed Matter PhysicsPhysical ChemistryThermodynamicsChemical ThermodynamicsDisordered SystemsMolecular ThermodynamicsOrder-disorder ThermodynamicsOrder-disorder TransformationsPhase TransitionsDisorder TransitionsOrder Parameter AnalysisOrder TransitionsOrder-disorder Transformation Kinetics
Order–disorder transitions in 1- and 2-methyladamantane, 1,3-dimethyladamantane, 1,3,5-trimethyladamantane, 1,3,5,7-tetramethyladamantane and in the 1-halogenoadamantanes have been investigated by differential scanning calorimetry. The effects of substituent groups on the disordered phase behaviour of these molecules are discussed.