A hydrogen bond scaffold supported synthetic heme FeIII–O2− adduct

Kaustuv Mittra, Sudipta Chatterjee, Subhra Samanta, Kushal Sengupta, Hridaynath Bhattacharjee, Abhishek Dey

Chemical Communications · 2012 · 49 citations · 25 references

Concepts

Abstract

A hydrogen bonded heme-Fe(III)-O(2)(-) adduct is stabilized and characterized using resonance Raman and EPR spectroscopy. The low O-O vibrations of this complex are quite different from those reported for other heme-Fe(III)-O(2)(-) adducts.

References

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