Angewandte Chemie International Edition in English · 1977 · 63 citations · 7 references
Combinatorial ChemistryBioorganic ChemistryEngineeringOrganic ChemistryChemistryHeterocycle ChemistryChemical DerivativeChemical EngineeringChemical MeasurementAbsolute ConfigurationPharmacologyAntibiotic VermiculinNatural Product SynthesisDithiane MethodHeterocyclicNatural SciencesFungicide PyrenophorinDerivative (Chemistry)Synthetic Chemistry
Two macrocyclic dilactides, the fungicide pyrenophorin (1) and the antibiotic vermiculin (2), have now been prepared in optically active form by use of the dithiane method. Their synthesis also proves that natural (1) has the (R,R) configuration and natural (2) the (S,S) configuration.
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Hans Loibner, Erich Zbiral · Helvetica Chimica Acta · 1976 · 229 citations
Systems Triphenylphosphin‐azodicarbonsäureester‐hydroxyverbindung, Biosynthesis, Bioorganic Chemistry +14
Total synthesis of (+-)-vermiculine
E. J. Corey, K. C. Nicolaou, Takeshi Toru · Journal of the American Chemical Society · 1975 · 87 citations