Concepedia

Catalytic Asymmetric Aldol Reaction of Silyl Enol Ethers with Aldehydes by the Use of Chiral Diamine Coordinated Tin(II) Triflate

Teruaki Mukaiyama, Shū Kobayashi, Hiromi Uchiro, Isamu Shiina

Chemistry Letters · 1990 · 93 citations · 4 references

DOI

Concepts

Abstract

Abstract Highly enantioselective aldol reaction of silyl enol ethers with aldehydes is performed by the use of a catalytic amount of chiral diamine coordinated tin(II) triflate according to a slow addition procedure.

References

4

Synthesis of .eta.1 oxygen-bound rhodium enolates. Applications to catalytic aldol chemistry

Greg A. Slough, Robert G. Bergman, Clayton H. Heathcock · Journal of the American Chemical Society · 1989 · 177 citations

, , +5

Asymmetric Allylation with a New Chiral Allylating Agent Prepared from Tin(II) Triflate, Chiral Diamine, and Allylaluminum

Nobuto Minowa, Teruaki Mukaiyama · Bulletin of the Chemical Society of Japan · 1987 · 86 citations · Full text

, , +7

Asymmetric aldol reaction of α-ketoesters with isocyanoacetate and isocyanoacetamide catalyzed by a chiral ferrocenylphosphine-gold(I) complex

Yoshihiko Ito, Masaya Sawamura, Hitoshi Hamashima et al. · Tetrahedron Letters · 1989 · 71 citations

, , +9

Catalytic use of tin(II) reagents in organic synthesis

Nobuharu Iwasawa, Takeshi Yura, Teruaki Mukaiyama · Tetrahedron · 1989 · 56 citations

, , +13